The Stieltjes outer measure on $\mathbb{R}$ with respect to $F$ is the D4361: Unsigned basic function
\begin{equation}
\mathcal{P}(\mathbb{R}) \to [0, \infty], \quad
E \mapsto \inf_{(a_0, b_0], (a_1, b_1], (a_2, b_2], \ldots \text{ is a cover for } E} \sum_{n = 0}^{\infty} F(b_n) - F(a_n)
\end{equation}